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1 \u6c27\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u8fdb\u5c55<\/p>\n
\u6c27\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u6750\u6599\u5177\u6709\u5b89\u5168\u6027\u80fd\u9ad8\u3001\u7a33\u5b9a\u6027\u826f\u597d\u3001\u6210\u672c\u4f4e\u5ec9\u3001\u73af\u5883\u53cb\u597d\u7b49\u4f18\u70b9\uff0c\u662f\u50a8\u80fd\u5e94\u7528\u7684\u7814\u7a76\u70ed\u70b9\u3002\u6c27\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u4e3b\u8981\u5305\u62ecNAS<\/u>ICON(sodium superionic conductor)\u578b\u7ed3\u6784\u6c27\u5316\u7269\u7535\u89e3\u8d28\u3001\u77f3\u69b4\u77f3\u7ed3\u6784\u6c27\u5316\u7269\u7535\u89e3\u8d28\u548c\u9499\u949b\u77ff\u7ed3\u6784\u6c27\u5316\u7269\u7535\u89e3\u8d28\u3002\u8fd1\u5341\u5e74\u6765\u9488\u5bf9\u6c27\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28\uff0c\u4e3b\u8981\u5f00\u5c55\u4e86\u5176\u5236\u5907\u3001\u6539\u6027\u3001\u5e94\u7528\u7b49\u65b9\u9762\u7684\u7814\u7a76\u3002<\/p>\n
1.1\u3000NASICON\u578b\u7ed3\u6784\u56fa\u4f53\u7535\u89e3\u8d28<\/p>\n
NASICON\u578b\u7ed3\u6784\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u901a\u5f0f\u4e3aLi[A2B3O12]\uff0c\u5176\u4e2dA\u3001B\u5206\u522b\u4ee3\u8868\u56db\u4ef7\u548c\u4e94\u4ef7\u9aa8\u67b6\u79bb\u5b50\u3002NASICON\u578b\u7ed3\u6784\u56fa\u4f53\u7535\u89e3\u8d28\u5236\u5907\u5de5\u827a\u7b80\u4fbf\uff0c\u6613\u4e8e\u52a0\u5de5\u5904\u7406\uff0c\u5bf9\u7a7a\u6c14\u7a33\u5b9a\uff0c\u70ed\u7a33\u5b9a\u6027\u548c\u529b\u5b66\u6027\u80fd\u826f\u597d\uff0c\u662f\u4e00\u7c7b\u91cd\u8981\u7684\u6c27\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u6750\u6599\u3002\u5e38\u89c1\u7684NASICON\u578b\u7ed3\u6784\u56fa\u4f53\u7535\u89e3\u8d28\u6839\u636e\u5316\u5b66\u7ec4\u6210\u53ef\u5206\u4e3aLiZr2(PO4)3(LZP)\uff0cLi<\/u>TI<\/u>2(PO4)3(LTP)\u548cLiGe2(PO4)3(LGP)\u3002\u5176\u4e2d\uff0cLTP\u548cLGP\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u660e\u663e\u9ad8\u4e8eLZP\uff0c\u4e3a\u8fd1\u5e74\u6765\u4e3b\u8981\u7814\u7a76\u7684NASICON\u578b\u6c27\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u4f53\u7cfb\u3002\u4e3a\u63d0\u9ad8LTP\u548cLGP\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u79bb\u5b50\u7535\u5bfc\u7387\uff0c\u6700\u5e38\u7528\u7684\u624b\u6bb5\u662f\u901a\u8fc7\u79bb\u5b50\u53d6\u4ee3\u6765\u8c03\u63a7\u79bb\u5b50\u4f20\u8f93\u901a\u9053\u3002\u5728LTP\u548cLGP\u4e2d\uff0c\u91c7\u7528Sc\u3001Al\u3001Y\u3001Ga\u7b49\u5bf9TI\u6216Ge\u8fdb\u884c\u90e8\u5206\u53d6\u4ee3\uff0c\u4ee5\u53ca\u91c7\u7528Si\u5bf9P\u8fdb\u884c\u90e8\u5206\u53d6\u4ee3\u5747\u53ef\u6709\u6548\u63d0\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u3002\u5176\u4e2d\uff0cAl3+\u53d6\u4ee3\u88ab\u8bc1\u660e\u662f\u6700\u6709\u6548\u7684\u624b\u6bb5\u3002\u56e0\u6b64\u5728LTP\u548cLGP\u4f53\u7cfb\u4e2d\uff0cLi1.3Al0.3TI1.7(PO4)3(LATP)\u548cLi1.5Al0.5G<\/u>e1.5(PO4)3(LAGP)\u5177\u6709\u5f88\u9ad8\u7684\u79bb\u5b50\u7535\u5bfc\u7387\uff0c\u4e24\u8005\u7535\u5bfc\u7387\u5747\u53ef\u8fbe\u5230\u7ea610-3 S\/cm\u91cf\u7ea7\uff0c\u662f\u5f53\u524d\u6700\u5e38\u89c1\u7684\u7814\u7a76\u4f53\u7cfb\u3002\u9664\u4e86\u4f20\u7edf\u5408\u6210<\/u>\u65b9\u6cd5\u4e4b\u5916\uff0cZhu\u7b49\u63d0\u51fa\u4e86\u4e00\u79cd\u5229\u7528NASICON\u9aa8\u67b6\u7ed3\u6784\u5236\u5907\u9ad8\u6027\u80fd\u56fa\u6001\u7535\u89e3\u8d28\u7684\u65b9\u6cd5\u3002\u7814\u7a76\u8005\u9996\u5148\u5236\u5907\u4e86NASICON\u7ed3\u6784\u7684Na3Zr2Si2PO12(NZSP)\u524d\u9a71\u4f53\uff0c\u7136\u540e\u901a\u8fc7\u9502\u94a0\u79bb\u5b50\u4ea4\u6362\u83b7\u5f97\u4e86\u540c\u6837\u5177\u6709NASICON\u7ed3\u6784\u7684Li3Zr2Si2PO12(LZSP)\u7535\u89e3\u8d28\u3002\u8be5\u65b9\u6cd5\u7684\u4f18\u70b9\u5728\u4e8e\u5728\u4fdd\u7559\u94a0\u8d85\u79bb\u5b50\u5bfc\u4f53\u6846\u67b6\u7ed3\u6784\u7684\u540c\u65f6\uff0c\u5f15\u5165\u4e86\u9502\u79bb\u5b50\u5e76\u7a33\u5b9a\u5728\u4f4e\u914d\u4f4d\u7ed3\u6784\u4e2d\uff0c\u83b7\u5f97\u4e86\u8f83\u5927\u7684\u9502\u79bb\u5b50\u4f20\u8f93\u8def\u5f84\uff0c\u4ece\u800c\u786e\u4fdd\u4e86\u5176\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u3002\u5408\u6210\u7684LZSP\u5728\u5ba4\u6e29\u4e0b\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u8fbe3.59\u00d710-3 S\/cm\uff0c\u6d3b\u5316\u80fd\u4e3a0.21 eV\u3002\u6b64\u5916\uff0cLZSP\u7ee7\u627f\u4e86NZSP\u4f18\u5f02\u7684\u7a7a\u6c14\u7a33\u5b9a\u6027\uff0c\u800c\u4e14\u5e94\u7528\u4e8e\u56fa\u6001\u7535\u6c60\u65f6\u8868\u73b0\u51fa\u4f18\u5f02\u7684\u5bf9\u9502\u7a33\u5b9a\u6027\u3001\u5faa\u73af\u7a33\u5b9a\u6027\u548c\u500d\u7387\u6027\u80fd\u3002<\/p>\n
\u867d\u7136LAGP\u548cLATP\u7535\u89e3\u8d28\u5177\u6709\u79bb\u5b50\u7535\u5bfc\u7387\u9ad8\u7684\u4f18\u70b9\uff0c\u4f46\u7531\u4e8e\u5185\u90e8\u5b58\u5728\u7684Ge4+\u548cTI4+\u5728\u70ed\u529b\u5b66\u4e0a\u5bf9\u9502\u4e0d\u7a33\u5b9a\uff0c\u6781\u6613\u88ab\u9502\u8fd8\u539f\u3002\u4e3a\u4e86\u63d0\u9ad8\u5176\u5b9e\u7528\u6027\uff0c\u73b0\u9636\u6bb5\u7684\u7814\u7a76\u4e3b\u8981\u901a\u8fc7\u7ec4\u5206\u4f18\u5316\u4ee5\u53ca\u5f15\u5165\u754c\u9762\u5c42\u7b49\u65b9\u5f0f\u6765\u6539\u5584\u5176\u8d1f\u6781\u7a33\u5b9a\u6027\u3002\u6548\u679c\u8f83\u597d\u7684\u754c\u9762\u5c42\u6750\u6599\u5305\u62ec\u975e\u6676\u6750\u6599\u3001\u6c1f\u5316\u7269\u6750\u6599\u3001\u6c2e\u5316\u7269\u6750\u6599\u3001\u6c27\u5316\u7269\u6750\u6599\u548c\u5176\u4ed6\u56fa\u4f53\u7535\u89e3\u8d28\u6750\u6599\u3002\u4e0d\u540c\u7684\u754c\u9762\u4fee\u9970\u5c42\u6750\u6599\u5bf9\u6bd4\u4e8e\u88681\u4e2d\u5217\u51fa\u3002Hao\u7b49\u62a5\u9053\u901a\u8fc7\u5728LATP\u56fa\u4f53\u7535\u89e3\u8d28\u8868\u9762\u6e85\u5c04ZnO\u5c42\uff0c\u6784\u5efa\u5177\u6709\u4f4e\u7535\u5b50\u7535\u5bfc\u548c\u826f\u597d\u6da6\u6e7f\u6027\u7684Zn@Li2O\u754c\u9762\u5c42\uff0c\u6709\u6548\u6539\u5584\u4e86LATP\/Li\u7684\u754c\u9762\u7a33\u5b9a\u6027(\u56fe1)\u3002Liu\u7b49\u901a\u8fc7ALD\u624b\u6bb5\u5728LATP\u56fa\u4f53\u7535\u89e3\u8d28\u8868\u9762\u5305\u8986Al2O3\u5c42\uff0c\u5305\u8986\u540e\u7684LATP\u7535\u89e3\u8d28\u5e94\u7528\u5728\u9502\u5bf9\u79f0\u7535\u6c60\u4e2d\u53ef\u5b9e\u73b0600\u5c0f\u65f6\u7a33\u5b9a\u5faa\u73af\u3002\u5728\u56fa\u4f53\u7535\u89e3\u8d28\u8868\u9762\u5305\u8986PEO\u3001LiPON\u7b49\u7535\u89e3\u8d28\u6750\u6599\u6765\u7a33\u5b9aNASICON\u578b\u7ed3\u6784\u56fa\u4f53\u7535\u89e3\u8d28\u4e0e\u91d1\u5c5e\u9502\u7684\u754c\u9762\uff0c\u4e5f\u662f\u4e00\u79cd\u6709\u6548\u7684\u65b9\u6cd5\u3002\u53e6\u5916\uff0c\u9274\u4e8e\u975e\u6676\u6750\u6599\u5177\u6709\u826f\u597d\u7684\u5bf9\u9502\u7a33\u5b9a\u6027\uff0c\u5236\u5907\u5bf9\u9502\u7a33\u5b9a\u7684\u975e\u6676NASICON\u578b\u7ed3\u6784\u56fa\u4f53\u7535\u89e3\u8d28\u6210\u4e3a\u4e00\u79cd\u6539\u5584\u754c\u9762\u7a33\u5b9a\u6027\u7684\u65b9\u6cd5\u30022019\u5e74\uff0cZhang\u7b49\u901a\u8fc7\u65cb\u6d82\u7684\u65b9\u5f0f\uff0c\u5728LAGP\u73bb\u7483\u9676\u74f7\u7247\u4e0a\u5747\u5300\u6d82\u8986\u4e86\u4e00\u5c42\u5bf9\u9502\u7a33\u5b9a\u7684\u975e\u6676LAGP\u5c42\u3002\u91c7\u7528\u6d82\u8986\u540eLAGP\u7535\u89e3\u8d28\u7ec4\u88c5\u7684\u56fa\u6001\u7535\u6c60\u5728\u5bb9\u91cf\u548c\u5faa\u73af\u7a33\u5b9a\u6027\u4e0a\u5747\u8fdc\u4f18\u4e8e\u672a\u6d82\u8986\u7535\u89e3\u8d28\u7ec4\u88c5\u7684\u56fa\u6001\u7535\u6c60\u3002<\/p>\n
\u88681 NASICON\/Li\u754c\u9762\u4e0d\u540c\u7684\u754c\u9762\u4fee\u9970\u5c42\u6750\u6599\u5bf9\u6bd4<\/p>\n
<\/p>\n
<\/p>\n
\u56fe1 (a) \u78c1\u63a7\u6e85\u5c04\u5728LATP\u8868\u9762\u5236\u5907\u8d85\u8584ZnO2\u793a\u610f\u56fe;(b) \u65e0ZnO\u5c42\u65f6\u9502\u91d1\u5c5e\u8d1f\u6781\u4e0eLATP\u754c\u9762\u53d8\u5316;(c) \u6709ZnO\u5c42\u65f6\u9502\u91d1\u5c5e\u8d1f\u6781\u4e0eLATP\u754c\u9762\u53d8\u5316<\/p>\n
1.2\u3000\u77f3\u69b4\u77f3\u7ed3\u6784\u56fa\u4f53\u7535\u89e3\u8d28<\/p>\n
\u77f3\u69b4\u77f3\u7ed3\u6784\u56fa\u4f53\u7535\u89e3\u8d28Li7La3Zr2O12(LLZO)\u5177\u6709\u826f\u597d\u7684\u79bb\u5b50\u4f20\u8f93\u6027\u80fd(10-3 S\/cm)\u3002\u9664\u5177\u6709\u6c27\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u4e00\u8d2f\u7684\u7a33\u5b9a\u6027\u4f18\u70b9\u5916\uff0c\u8fd8\u8868\u73b0\u51fa\u8fdc\u4f18\u4e8e\u5176\u4ed6\u79cd\u7c7b\u6c27\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u5bf9\u9502\u91d1\u5c5e\u7a33\u5b9a\u6027\uff0c\u56e0\u6b64\u5176\u5728\u56fa\u6001\u7535\u6c60\u5e94\u7528\u4e2d\u6781\u5177\u6f5c\u529b\u3002LLZO\u5b58\u5728\u7acb\u65b9\u76f8(c-LLZO)\u548c\u56db\u65b9\u76f8(t-LLZO)\u4e24\u79cd\u6676\u4f53<\/u>\u7ed3\u6784\u3002\u5176\u4e2d\uff0cc-LLZO\u5728\u5ba4\u6e29\u4e0b\u662f\u4e9a\u7a33\u5b9a\u76f8\uff0c\u79bb\u5b50\u7535\u5bfc\u7387\u66f4\u9ad8;\u800ct-LLZO\u5c5e\u4e8e\u5ba4\u6e29\u7a33\u5b9a\u76f8\uff0c\u79bb\u5b50\u7535\u5bfc\u7387\u4f4e\u3002\u8bbe\u6cd5\u5728\u5ba4\u6e29\u4e0b\u7a33\u5b9a\u7acb\u65b9\u76f8\uff0c\u4ee5\u63d0\u9ad8\u5176\u79bb\u5b50\u7535\u5bfc\u7387\u662f\u5f53\u524dLLZO\u6750\u6599\u5236\u5907\u9886\u57df\u7684\u7814\u7a76\u91cd\u70b9\u3002\u53e6\u5916\uff0c\u867d\u7136LLZO\u5bf9\u9502\u91d1\u5c5e\u7a33\u5b9a\uff0c\u4f46\u5185\u90e8\u5b58\u5728\u7684\u7f3a\u9677\u4f9d\u7136\u4f1a\u5bfc\u81f4\u679d\u6676\u7684\u751f\u957f\uff0c\u6700\u7ec8\u5bfc\u81f4\u56fa\u6001\u7535\u6c60\u5931\u6548\uff0c\u56e0\u800c\u63d0\u9ad8LLZO\u81f4\u5bc6\u5ea6\u4e5f\u662f\u5f53\u524d\u91cd\u8981\u7684\u7814\u7a76\u65b9\u5411\u3002\u5728\u91c7\u7528LLZO\u6750\u6599\u7ec4\u88c5\u56fa\u6001\u7535\u6c60\u65f6\uff0c\u5176\u4e0e\u9502\u91d1\u5c5e\u8d1f\u6781\u826f\u597d\u7684\u754c\u9762\u63a5\u89e6\u5bf9\u9502\u79bb\u5b50\u5728\u754c\u9762\u7684\u5747\u5300\u4f20\u8f93\u6781\u4e3a\u5173\u952e\u3002\u7531\u4e8eLLZO\u4e0e\u9502\u91d1\u5c5e\u63a5\u89e6\u5c5e\u4e8e\u70b9\u5bf9\u70b9\u7684\u56fa-\u56fa\u63a5\u89e6\uff0c\u63a5\u89e6\u9762\u79ef\u5c0f\uff0c\u4e14\u4e24\u8005\u754c\u9762\u80fd\u4e0d\u5339\u914d\u4f7f\u5f97\u4e0d\u80fd\u5b9e\u73b0\u6da6\u6e7f\uff0c\u4f1a\u5bfc\u81f4\u754c\u9762\u963b\u6297<\/u>\u8f83\u5927\u548c\u754c\u9762\u5904\u9502\u679d\u6676\u7684\u751f\u957f\u3002\u56e0\u6b64\uff0c\u901a\u8fc7\u51cf\u5c0fLLZO\u4e0e\u9502\u91d1\u5c5e\u4e4b\u95f4\u754c\u9762\u80fd\u7684\u5dee\u522b\uff0c\u6539\u5584\u4e24\u8005\u95f4\u6da6\u6e7f\u6027\uff0c\u4f18\u5316\u754c\u9762\u63a5\u89e6\uff0c\u662f\u5b9e\u73b0LLZO\u5e94\u7528\u7684\u91cd\u8981\u524d\u63d0\u3002<\/p>\n
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\u88682 LLZO\/Li\u754c\u9762\u4e0d\u540c\u7684\u6da6\u6e7f\u5c42\u6750\u6599\u5bf9\u6bd4<\/p>\n
<\/p>\n
<\/p>\n
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1.3\u3000\u9499\u949b\u77ff\u7ed3\u6784\u56fa\u4f53\u7535\u89e3\u8d28<\/p>\n
\u9499\u949b\u77ff\u7ed3\u6784\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u901a\u5f0f\u4e3aLi3xLa2\/3-xTiO3(LLTO)\u3002\u9499\u949b\u77ff\u7ed3\u6784\u56fa\u4f53\u7535\u89e3\u8d28\u7535\u5bfc\u7387\u8f83\u9ad8\uff0c\u70ed\u7a33\u5b9a\u6027\u548c\u529b\u5b66\u6027\u80fd\u826f\u597d\uff0c\u4f46\u5236\u5907\u6e29\u5ea6\u8f83\u9ad8\u3002\u4e3a\u63d0\u9ad8LLTO\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u79bb\u5b50\u7535\u5bfc\u7387\uff0c\u901a\u5e38\u91c7\u7528\u7684\u7b56\u7565\u5305\u62ec\u79bb\u5b50\u53d6\u4ee3\u3001\u590d\u5408\u548c\u70e7\u7ed3\u6c14\u6c1b\u8c03\u63a7\u3002\u7814\u7a76\u8868\u660e\uff0c\u91c7\u7528Pr\u3001Nd\u548cY\u7b49\u5bf9LLTO\u4e2d\u7684La\u8fdb\u884c\u90e8\u5206\u53d6\u4ee3\uff0c\u6216\u8005\u91c7\u7528Al\u3001Zr\u3001Cr\u3001Nb\u3001Ta\u3001W\u7b49\u5bf9LLTO\u4e2d\u7684Ti\u8fdb\u884c\u90e8\u5206\u53d6\u4ee3\uff0c\u53ef\u6709\u6548\u63d0\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u5bf9La\u4f4d\u53d6\u4ee3\u6765\u8bf4\uff0c\u53d6\u4ee3\u79bb\u5b50\u7684\u534a\u5f84\u8d8a\u5927\uff0c\u9502\u79bb\u5b50\u4f20\u8f93\u901a\u9053\u74f6\u9888\u5c3a\u5bf8\u8d8a\u5927\uff0c\u8d8a\u80fd\u63d0\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u3002\u76f8\u53cd\uff0c\u5bf9Ti\u4f4d\u53d6\u4ee3\u6765\u8bf4\uff0c\u53d6\u4ee3\u79bb\u5b50\u7684\u534a\u5f84\u8d8a\u5c0f\uff0c\u4f7fTi\u2014O\u539f\u5b50\u95f4\u8ddd\u79bb\u7f29\u77ed\uff0cTi\u2014O\u952e\u5f3a\u5ea6\u5f97\u5230\u589e\u5f3a\uff0c\u8d8a\u6709\u5229\u4e8e\u63d0\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u3002\u4e0eLLTO\u8f83\u9ad8\u7684\u6676\u7c92\u7535\u5bfc\u7387\u76f8\u6bd4\uff0cLLTO\u7684\u6676\u754c\u7535\u5bfc\u7387\u4e00\u822c\u8981\u4f4e2\uff5e3\u4e2a\u6570\u91cf\u7ea7\uff0c\u662fLLTO\u79bb\u5b50\u7535\u5bfc\u7387\u63d0\u9ad8\u7684\u91cd\u70b9\u65b9\u5411\u3002\u901a\u8fc7\u590d\u5408LiF\u7b49\u589e\u52a0\u9502\u79bb\u5b50\u6d53\u5ea6\uff0c\u6216\u590d\u5408\u9502\u787c\u6c27\u5316\u7269(Li2O-B2O3)\u7b49\u4f4e\u7194\u70b9\u52a9\u5242\u6765\u6539\u5584\u70e7\u7ed3\u6027\u80fd\u3001\u63d0\u9ad8\u81f4\u5bc6\u5ea6\uff0c\u5747\u88ab\u8bc1\u660e\u53ef\u63d0\u9ad8\u6676\u754c\u7535\u5bfc\u7387\u3002\u6b64\u5916\uff0c\u901a\u8fc7\u6392\u9664\u70e7\u7ed3\u6c14\u6c1b\u4e2d\u7684\u6c34\u548cCO2\uff0c\u907f\u514d\u4f4e\u7535\u5bfcLi2CO3\u7684\u751f\u6210\u4e5f\u6709\u5229\u4e8e\u79bb\u5b50\u7535\u5bfc\u7387\u7684\u63d0\u9ad8\u3002<\/p>\n
\u4e0eNASICON\u578b\u7ed3\u6784\u56fa\u4f53\u7535\u89e3\u8d28\u7c7b\u4f3c\uff0cLLTO\u56fa\u4f53\u7535\u89e3\u8d28\u7531\u4e8e\u5b58\u5728\u6613\u88ab\u8fd8\u539f\u7684Ti4+\uff0c\u4e5f\u5b58\u5728\u5bf9\u9502\u754c\u9762\u7a33\u5b9a\u6027\u95ee\u9898\u3002Yan\u7b49\u63d0\u51fa\u91c7\u7528\u6df7\u5408\u79bb\u5b50\/\u7535\u5b50\u5bfc\u4f53\u5c42\u6765\u89e3\u51b3\u7a33\u5b9a\u6027\u95ee\u9898\u3002\u7814\u7a76\u4e2d\u4ee5\u7532\u82ef\u4e3a\u50ac\u5316\u5242\uff0c\u5f15\u53d1\u4e86LLTO\u4e0e\u91d1\u5c5e\u9502\u7684\u53cd\u5e94\uff0c\u5f62\u6210\u4e86Li0.35La0.52[V]0.13TiO3\u6df7\u5408\u79bb\u5b50\/\u7535\u5b50\u5bfc\u4f53\u5c42\u3002\u8be5\u6df7\u5408\u79bb\u5b50\/\u7535\u5b50\u5bfc\u4f53\u5c42\u7f13\u51b2\u4e86\u9502\u79bb\u5b50\u6d53\u5ea6\u68af\u5ea6\uff0c\u5e76\u4f7f\u9502\u91d1\u5c5e\u8868\u9762\u7684\u4e8c\u6b21\u7535\u6d41\u5747\u5300\u5206\u5e03\uff0c\u6709\u6548\u6291\u5236\u4e86\u526f\u53cd\u5e94\u53d1\u751f\u548c\u679d\u6676\u751f\u957f\u3002\u76ee\u524d\uff0cLLTO\u7684\u4e3b\u8981\u5408\u6210\u65b9\u6cd5\u90fd\u9700\u8981\u8f83\u9ad8\u7684\u70e7\u7ed3\u6e29\u5ea6\uff0c\u5bb9\u6613\u5bfc\u81f4\u9502\u7684\u6325\u53d1\u548c\u6676\u754c\u963b\u6297\u7684\u63d0\u9ad8\u3002\u56e0\u6b64\uff0c\u964d\u4f4e\u70e7\u7ed3\u6e29\u5ea6\uff0c\u5e76\u964d\u4f4e\u6676\u754c\u963b\u6297\u5c06\u662f\u672a\u6765LLTO\u56fa\u4f53\u7535\u89e3\u8d28\u7814\u7a76\u7684\u91cd\u70b9\u3002<\/p>\n
2 \u786b\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u8fdb\u5c55<\/p>\n
\u786b\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u5728\u5ba4\u6e29\u4e0b\u5177\u6709\u8f83\u9ad8\u7684\u79bb\u5b50\u7535\u5bfc\u7387\uff0c\u8303\u56f4\u4ece10-4\u523010-2 S\/cm\u3002\u540c\u65f6\uff0c\u786b\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u5177\u6709\u53ef\u5ffd\u7565\u7684\u7535\u5b50\u7535\u5bfc\u7387\u548c\u826f\u597d\u7684\u529b\u5b66\u6027\u80fd\uff0c\u6709\u5229\u4e8e\u5168\u56fa\u6001\u7535\u6c60\u4e2d\u7535\u6781\/\u7535\u89e3\u8d28\u5f62\u6210\u826f\u597d\u7684\u56fa-\u56fa\u63a5\u89e6\u754c\u9762\uff0c\u4ece\u800c\u4f18\u5316\u5168\u56fa\u6001\u7535\u6c60\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002\u56e0\u6b64\uff0c\u8bb8\u591a\u5de5\u4f5c\u4ece\u786b\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u4f53\u7cfb\u5165\u624b\uff0c\u81f4\u529b\u4e8e\u5f00\u53d1\u51fa\u5177\u6709\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\uff0c\u5bbd\u7535\u5316\u5b66\u7a97\u53e3\uff0c\u5177\u6709\u826f\u597d\u5316\u5b66\u7a33\u5b9a\u6027\u548c\u7a7a\u6c14\u7a33\u5b9a\u6027\u7684\u7406\u60f3\u56fa\u4f53\u7535\u89e3\u8d28\u6750\u6599\u3002\u56fe3\u6574\u7406\u4e862011\u20142021\u5e74\u786b\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u7814\u7a76\u4e2d\u5177\u6709\u4ee3\u8868\u6027\u7684\u5de5\u4f5c\uff0c\u4ee5\u4e0b\u5c06\u6309\u7167Li-P-S\u4e8c\u5143\u786b\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28\uff0cLi10GeP2S12\uff0cLi6PS5X(X=Cl\uff0cBr\uff0cI)\u4e09\u4e2a\u4f53\u7cfb\u5206\u7c7b\u5206\u522b\u4ecb\u7ecd\u786b\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u8fd1\u5341\u5e74\u5de5\u4f5c\u8fdb\u5c55\u3002<\/p>\n
<\/p>\n
\u56fe3 \u8fd1\u5341\u5e74\u786b\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u91cd\u8981\u8fdb\u5c55<\/p>\n
2.1\u3000Li-P-S\u4f53\u7cfb<\/p>\n
Li2S-P2S5\u4f53\u7cfb\u786b\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u7814\u7a76\u59cb\u4e8e1981\u5e74\uff0c\u8fd1\u5e74\u6765\u5e7f\u53d7\u5173\u6ce8\u7684\u662f\u5177\u6709\u826f\u597d\u5bf9\u9502\u7a33\u5b9a\u6027\u548c\u5bf9\u7a7a\u6c14\u7a33\u5b9a\u6027\u768475Li2S-25P2S5(Li3PS4)\u4f53\u7cfb\u6750\u6599\u548c\u7535\u5bfc\u7387\u8f83\u9ad8\u768470Li2S-30P2S5(Li7P3S11)\u4f53\u7cfb\u6750\u6599\u3002<\/p>\n
\u65e9\u671fLi3PS4\u7535\u89e3\u8d28\u6750\u6599\u4e3b\u8981\u901a\u8fc7\u56fa\u76f8\u6cd5\u5408\u6210\uff0c\u9897\u7c92\u5c3a\u5bf8\u8f83\u5927\uff0c\u7535\u5bfc\u7387\u8f83\u4f4e\u3002Liu\u7b49\u91c7\u7528\u6db2\u76f8\u6cd5\u5408\u6210\u4e86\u5177\u6709\u7eb3\u7c73\u5b54\u9699\u7ed3\u6784\u7684Li3PS4\uff0c\u5c06\u7535\u89e3\u8d28\u6750\u6599\u5c3a\u5bf8\u964d\u4f4e\u5230\u7eb3\u7c73\u7ea7\uff0c\u7a33\u5b9a\u4e86\u9ad8\u7535\u5bfc\u7387\u7684\u03b2\u76f8\uff0c\u540c\u65f6\u4f7f\u7535\u89e3\u8d28\u6750\u6599\u6bd4\u8868\u9762\u79ef\u589e\u52a0\uff0c\u63d0\u9ad8\u4e86\u8868\u9762\u7535\u5bfc\u6027\u80fd\uff0c\u5236\u5907\u5f97\u5230\u7684Li3PS4\u7535\u89e3\u8d28\u5ba4\u6e29\u79bb\u5b50\u7535\u5bfc\u7387\u4e3a1.6\u00d710-4 S\/cm\u3002\u9664\u4e86\u5ba4\u6e29\u79bb\u5b50\u7535\u5bfc\u7387\u548c\u9897\u7c92\u5c3a\u5bf8\uff0c\u8fd1\u5e74\u6765\u9488\u5bf9Li3PS4\u5bf9\u9502\u7a33\u5b9a\u6027\u6539\u6027\u7684\u7814\u7a76\u4e5f\u53d7\u5230\u5e7f\u6cdb\u5173\u6ce8\u3002Rangasamy\u7b49\u901a\u8fc7\u56fa\u76f8\u6cd5\u5728Li3PS4\u4e2d\u63ba\u6742LiI\uff0c\u5408\u6210\u4e86Li7P2S8I\u73bb\u7483\u9676\u74f7\u7535\u89e3\u8d28\uff0c\u5177\u67096.3\u00d710-4 S\/cm\u7684\u5ba4\u6e29\u79bb\u5b50\u7535\u5bfc\uff0c\u540c\u65f6\uff0c\u542bI\u76f8\u7684\u5b58\u5728\u4f7fLi7P2S8I\u7535\u89e3\u8d28\u7684\u5bf9\u9502\u7a33\u5b9a\u6027\u63d0\u9ad8\u3002<\/p>\n
\u4e0eLi3PS4\u7535\u89e3\u8d28\u76f8\u6bd4\uff0cLi7P3S11\u7535\u89e3\u8d28\u5177\u6709\u66f4\u9ad8\u7684\u5ba4\u6e29\u79bb\u5b50\u7535\u5bfc\u7387\u30022014\u5e74\uff0cSeino\u7b49\u901a\u8fc7\u8c03\u6574\u70ed\u5904\u7406\u6761\u4ef6\uff0c\u964d\u4f4e\u4e86\u56fa\u4f53\u7535\u89e3\u8d28\u6676\u754c\u963b\u6297\u53ca\u7535\u89e3\u8d28\u4f53\u76f8\u7a7a\u9699\u5bf9\u7535\u89e3\u8d28\u79bb\u5b50\u7535\u5bfc\u7387\u7684\u5f71\u54cd\uff0c\u5c06Li7P3S11\u7535\u89e3\u8d28\u7684\u5ba4\u6e29\u79bb\u5b50\u7535\u5bfc\u7387\u8fdb\u4e00\u6b65\u63d0\u5347\u81f31.7\u00d710-2 S\/cm\u3002\u5728\u7535\u89e3\u8d28\u9897\u7c92\u5c3a\u5bf8\u63a7\u5236\u65b9\u9762\uff0cYao\u7b49\u901a\u8fc7\u6db2\u76f8\u6cd5\u5408\u6210Li7P3S11\u7535\u89e3\u8d28\uff0c\u5176\u9897\u7c92\u5c3a\u5bf8\u4e3a400 nm\uff5e1 \u03bcm\uff0c\u540c\u65f6\u5177\u67091.5\u00d710-3 S\/cm\u7684\u9ad8\u5ba4\u6e29\u79bb\u5b50\u7535\u5bfc\u7387\uff0c\u5e76\u901a\u8fc7\u6db2\u76f8\u6cd5\u5c06\u7535\u89e3\u8d28\u5305\u8986\u5728Co9S8\u7535\u6781\u6750\u6599\u8868\u9762\uff0c\u83b7\u5f97\u4e86\u66f4\u8fde\u7eed\u7684\u9502\u79bb\u5b50\u4f20\u8f93\u901a\u9053\uff0c\u4ece\u800c\u4f7f\u5168\u56fa\u6001\u7535\u6c60\u5b9e\u73b0\u66f4\u597d\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002<\/p>\n
2.2\u3000Li11-xM2-xP1+xS12 (M = Ge, Sn, Si) \u4f53\u7cfb<\/p>\n
\u4e3a\u4e86\u8fdb\u4e00\u6b65\u4f18\u5316Li2S-P2S5\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u53ca\u5176\u4ed6\u7535\u5316\u5b66\u6027\u80fd\uff0c\u8bb8\u591a\u5de5\u4f5c\u901a\u8fc7\u5f15\u5165GeS2\u3001SiS2\u3001SnS2\u6216Al2S3\u7b49\u7b2c\u4e09\u7ec4\u5206\u83b7\u5f97\u4e09\u5143\u4f53\u7cfb\u3002\u5176\u4e2dLi2S-GeS2-P2S5\u5177\u6709\u5f88\u9ad8\u7684\u79bb\u5b50\u7535\u5bfc\u7387\uff0c\u662f\u4e09\u5143\u786b\u5316\u7269\u7535\u89e3\u8d28\u4e2d\u7814\u7a76\u6700\u591a\u7684\u4f53\u7cfb\u30022011\u5e74\u65e5\u672c\u4e1c\u4eac\u5de5\u4e1a\u5927\u5b66\u7684Kamaya\u7b49\u5236\u5907\u51faLi10GeP2S12\u7535\u89e3\u8d28\uff0c\u5176\u7535\u5bfc\u7387\u9ad8\u8fbe1.2\u00d710-2 S\/cm\uff0c\u662f\u7b2c\u4e00\u79cd\u79bb\u5b50\u7535\u5bfc\u7387\u53ef\u4e0e\u6db2\u6001\u7535\u89e3\u6db2\u76f8\u5ab2\u7f8e\u7684\u56fa\u4f53\u7535\u89e3\u8d28\u3002Li10GeP2S12\u7535\u89e3\u8d28\u5728\u8f83\u4f4e\u7684\u6e29\u5ea6\u4e0b\u4e5f\u8868\u73b0\u51fa\u9ad8\u79bb\u5b50\u5bfc\u7535\u6027\uff0c\u5728-30 \u2103\u4e0b\u4e3a1.0\u00d710-3 S\/cm\uff0c-45 \u2103\u4e0b\u4e3a4.0\u00d710-4 S\/cm\u3002\u867d\u7136Li10GeP2S12\u5177\u6709\u8f83\u9ad8\u7684\u79bb\u5b50\u7535\u5bfc\u7387\uff0c\u4f46Ge\u5143\u7d20\u7684\u9ad8\u6210\u672c\u548c\u5bf9\u9502\u91d1\u5c5e\u7684\u4e0d\u7a33\u5b9a\u6027\u9650\u5236\u4e86\u5176\u5728\u5168\u56fa\u6001\u9502\u7535\u6c60\u4e2d\u7684\u5927\u89c4\u6a21\u5e94\u7528\u3002\u56e0\u6b64\uff0c\u8bb8\u591a\u5177\u6709\u6210\u672c\u4f18\u52bf\u7684\u5143\u7d20\u88ab\u7528\u6765\u53d6\u4ee3Ge\u5143\u7d20\u3002\u4e3a\u4e86\u964d\u4f4e\u7535\u89e3\u8d28\u7684\u6210\u672c\uff0c\u540c\u65f6\u4fdd\u8bc1\u7535\u89e3\u8d28\u9ad8\u5ba4\u6e29\u79bb\u5b50\u7535\u5bfc\u7387\uff0cKato\u7b49\u4e8e2016\u5e74\u901a\u8fc7\u91c7\u7528Si\u3001Cl\u540c\u65f6\u53d6\u4ee3Ge\u548cS\uff0c\u5236\u5907\u51faLi9.54Si1.74P1.44S11.7Cl0.3\u7535\u89e3\u8d28\uff0c\u5176\u6676\u4f53\u7ed3\u6784\u4e0eLi10GeP2S12\u7535\u89e3\u8d28\u76f8\u4f3c\uff0c\u5177\u670925\u00d710-3 S\/cm\u7684\u8d85\u9ad8\u5ba4\u6e29\u79bb\u5b50\u7535\u5bfc\u7387\u3002\u5728\u6b64\u57fa\u7840\u4e0a\uff0cLi\u7b49\u901a\u8fc7O\u53d6\u4ee3\u5177\u6709Li10GeP2S12\u6784\u578b\u7684Li9.54Si1.74P1.44S11.7Cl0.3\u4e2d\u7684S\uff0c\u5408\u6210\u4e86Li9.54Si1.74P1.44S11.7-zCl0.3Oz\u56fa\u6001\u7535\u89e3\u8d28\u6750\u6599(0<\/p>\n
2.3\u3000Li6PS5X(X=Cl, Br, I)\u4f53\u7cfb<\/p>\n
\u786b\u94f6\u9517\u77ff\u76f8Li6PS5X(X=Cl, Br, I)\u7535\u89e3\u8d28\u662f\u5177\u6709\u53e6\u4e00\u79cd\u6676\u4f53\u7ed3\u6784\u7684\u786b\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28\uff0c\u7531\u5177\u6709\u8f83\u9ad8Ag+\u5bfc\u7535\u6027\u7684Ag8GeS6\u6f14\u53d8\u5f97\u5230\u3002\u4ee5Li\u66ff\u4ee3Ag\u5143\u7d20\uff0cP\u66ff\u4ee3Ge\u5143\u7d20\uff0c\u5f97\u5230Li7PS6\uff0c\u786b\u94f6\u9517\u77ff\u9502\u578b\u5316\u5408\u7269\u5177\u6709\u8f83\u9ad8\u7684\u9502\u79bb\u5b50\u7535\u5bfc\u7387\u3002\u7136\u800c\uff0cLi7PS6\u5728\u9ad8\u6e29\u4e0b\u4e3a\u7acb\u65b9\u76f8\uff0c\u5728\u4f4e\u6e29\u4e0b\u4f1a\u8f6c\u53d8\u4e3a\u6b63\u4ea4\u6676\u76f8\uff0c\u6e29\u5ea6\u7a33\u5b9a\u6027\u8f83\u5dee\u30022008\u5e74\uff0cDeiseroth\u7b49\u4ee5\u5364\u7d20\u9634\u79bb\u5b50\u90e8\u5206\u53d6\u4ee3S2-\u79bb\u5b50\uff0c\u9996\u6b21\u5f97\u5230\u901a\u5f0f\u4e3aLi6PS5X(X=Cl\uff0cBr\uff0cI)\u7684\u786b\u94f6\u9517\u77ff\u9502\u578b\u5316\u5408\u7269\u3002\u76f8\u6bd4\u4e8eLi10GeP2S12\u7535\u89e3\u8d28\uff0c\u786b\u94f6\u9517\u77ff\u76f8\u5177\u6709\u66f4\u52a0\u4f18\u826f\u7684\u5316\u5b66\u548c\u7535\u5316\u5b66\u7a33\u5b9a\u6027\uff0c\u56e0\u6b64\u5f15\u8d77\u4f17\u591a\u7814\u7a76\u8005\u5173\u6ce8\uff0c\u6210\u4e3a\u6700\u8fd1\u51e0\u5e74\u7684\u7814\u7a76\u70ed\u70b9\u3002<\/p>\n
\u5bf9\u786b\u94f6\u9517\u77ff\u76f8Li6PS5X(X=Cl\uff0cBr\uff0cI)\u7535\u89e3\u8d28\u6765\u8bf4\uff0c\u5364\u7d20\u4f4d\u5143\u7d20\u5bf9\u5176\u6676\u4f53\u7ed3\u6784\u548c\u5ba4\u6e29\u79bb\u5b50\u7535\u5bfc\u7387\u6709\u8f83\u5927\u5f71\u54cd\uff0c\u5f53\u5364\u7d20\u4f4dX=Cl\u6216Br\u65f6\uff0c\u7531\u4e8eCl-\u6216Br-\u79bb\u5b50\u534a\u5f84\u5c0f\uff0cS2-\u548cX -\u6392\u5217\u5177\u6709\u4e00\u5b9a\u7684\u65e0\u5e8f\u6027\uff0c\u4fbf\u4e8e\u9502\u79bb\u5b50\u4f20\u5bfc\uff0c\u5176\u5ba4\u6e29\u79bb\u5b50\u7535\u5bfc\u7387\u7ea610-3 S\/cm;\u5f53\u5364\u7d20\u4f4d\u4e3aI\u65f6\uff0c\u6676\u4f53\u7ed3\u6784\u4e2dS2-\u548cX -\u6709\u5e8f\u6392\u5217\uff0c\u5ba4\u6e29\u79bb\u5b50\u7535\u5bfc\u7387\u7ea610-5 S\/cm\u3002\u7531\u6b64\u53ef\u89c1\uff0cX -\u4e0eS2-\u6392\u5217\u65e0\u5e8f\u5ea6\u5bf9\u9502\u79bb\u5b50\u5728\u6676\u683c\u4e2d\u7684\u6269\u6563\u5177\u6709\u91cd\u8981\u7684\u5f71\u54cd\u3002Ad<\/u>eli\u7b49\u62a5\u9053\u4e86\u4e00\u79cd\u5bcc\u542b\u5364\u7d20\u7684\u786b\u94f6\u9517\u77ff\u7c7b\u56fa\u4f53\u7535\u89e3\u8d28Li6-xPS5-xCl1+x\uff0c\u901a\u8fc7\u5355\u4ef7\u7684Cl-\u90e8\u5206\u53d6\u4ee3\u4e8c\u4ef7\u7684S2-\uff0c\u6676\u4f53\u7ed3\u6784\u4e2d\u65e0\u5e8f\u4f4d\u70b9\u548c\u9502\u7a7a\u4f4d\u589e\u591a\uff0c\u51cf\u5f31\u4e86\u6e38\u79bb\u9502\u79bb\u5b50\u540c\u5468\u56f4\u9aa8\u67b6\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u56e0\u6b64\u53ef\u4f7f\u9502\u79bb\u5b50\u6269\u6563\u7cfb\u6570\u5f97\u5230\u63d0\u9ad8\u3002\u51b7\u538b<\/u>\u4e0b\uff0cLi5.5PS4.5Cl1.5\u5728298 K\u65f6\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u4e3a(9.4\u00b10.1)\u00d710-3 S\/cm\uff0c\u70e7\u7ed3\u540e\u4e3a(12.0\u00b10.2)\u00d710-3 S\/cm\u3002\u57fa\u4e8e\u5bcc\u542b\u5364\u7d20\u7684\u786b\u94f6\u9517\u77ff\u76f8\u7535\u89e3\u8d28\uff0cPatel\u7b49\u62a5\u9053\u4e86Li6-xPS5-xClBrx(0\u2264x\u22640.8)\u7535\u89e3\u8d28\uff0c\u5176\u4e2dLi5.3PS4.3ClBr0.7\u572825 \u2103\u4e0b\u670924\u00d710-3 S\/cm\u7684\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\uff0c\u4ee5\u53ca0.155 eV\u7684\u6781\u4f4e\u9502\u8fc1\u79fb\u52bf\u5792\u3002\u5f15\u5165\u6eb4\u539f\u5b50\u540e\uff0cLi6-xPS5-xClBrx(0\u2264x\u22640.7)\u4ecd\u4fdd\u6301Li6PS5Cl\u7ed3\u6784\u3002Cl-\u3001Br-\u4e0eS2-\u5171\u540c\u5360\u4f4d\u57284a\/4d\uff0c\u4e14\u5728x\u63a5\u8fd10.7\u65f6\u4ea7\u751f\u4e86\u7c7b\u6db2\u76f8\u7684\u9502\u4e9a\u6676\u683c\u7ed3\u6784\uff0c\u589e\u5f3a\u4e86\u9502\u79bb\u5b50\u8fc1\u79fb\u80fd\u529b\u3002\u6b64\u5916\uff0c\u9634\u79bb\u5b50\u79cd\u7c7b\u7684\u591a\u6837\u5316\u4ee5\u53ca\u9502\u7a7a\u4f4d\u7684\u4ea7\u751f\u8bf1\u53d1\u4e86Li6-xPS5-xClBrx\u4e2d\u8fc7\u914d\u4f4d\u4e0e\u914d\u4f4d\u71b5\u7684\u4ea7\u751f\uff0c\u8fd9\u4e9b\u4e5f\u90fd\u589e\u5f3a\u4e86\u5176\u9502\u79bb\u5b50\u4f20\u8f93\u80fd\u529b\u3002<\/p>\n
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<\/p>\n
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3 \u805a\u5408\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u8fdb\u5c55<\/p>\n
3.1\u3000\u805a\u5408\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u7b80\u4ecb<\/p>\n
\u76f8\u8f83\u4e8e\u65e0\u673a\u56fa\u4f53\u7535\u89e3\u8d28\uff0c\u6eb6\u89e3\u9502\u76d0\u7684\u56fa\u4f53\u805a\u5408\u7269\u7535\u89e3\u8d28(SPE)\u5177\u6709\u67d4\u97e7\u6027\u597d\u3001\u8d28\u91cf\u8f7b\u3001\u6210\u672c\u4f4e\u4ee5\u53ca\u6613\u4e8e\u52a0\u5de5\u7b49\u4f18\u52bf\u3002\u5728\u5404\u79cd\u805a\u5408\u7269\u57fa\u4f53\u5982\u805a\u73af\u6c27\u4e59\u70f7(PEO)\u3001\u805a\u4e19\u70ef\u8148(PAN)\u3001\u805a\u504f\u6c1f\u4e59\u70ef(PVDF)\u3001\u805a(\u504f\u4e8c\u6c1f\u4e59\u70ef-\u516d\u6c1f\u4e19\u70ef)(PVDF-HFP)\u548c\u805a\u7532\u57fa\u4e19\u70ef\u9178\u7532\u916f(PMMA)\u4e2d\uff0cPEO\u542b\u6709\u4e59\u6c27\u57fa\u94fe\u6bb5\uff0c\u5bf9\u9502\u76d0\u5177\u6709\u9ad8\u7684\u6eb6\u89e3\u80fd\u529b\uff0c\u662f\u7814\u7a76\u6700\u4e3a\u5e7f\u6cdb\u7684\u805a\u5408\u7269\u57fa\u4f53\u6750\u6599\u3002\u65e9\u57281973\u5e74\uff0cFenton\u7b49\u7387\u5148\u53d1\u73b0\u90e8\u5206\u78b1\u91d1\u5c5e\u76d0\u53ef\u4ee5\u548cPEO\u5f62\u6210\u805a\u5408\u7269\u548c\u76d0\u7684\u7edc\u5408\u7269\uff0c\u5e76\u5bf9\u5176\u79bb\u5b50\u5bfc\u7535\u6027\u8fdb\u884c\u4e86\u7814\u7a76\u3002\u4f46\u65e9\u671f\u5236\u5907\u7684PEO\u57fa\u805a\u5408\u7269\u7535\u89e3\u8d28\u7684\u5ba4\u6e29\u79bb\u5b50\u7535\u5bfc\u7387\u4ec5\u4ec5\u53ea\u670910-7\uff5e10-5 S\/cm\uff0c\u8fd9\u4e3b\u8981\u7531\u4e8ePEO\u662f\u4e00\u79cd\u6613\u4e8e\u7ed3\u6676\u7684\u805a\u5408\u7269\u57fa\u4f53\uff0c\u5728\u8f83\u4f4e\u7684\u6e29\u5ea6\u4e0bPEO\u57fa\u805a\u5408\u7269\u7535\u89e3\u8d28\u5185\u4ec5\u542b\u6709\u6781\u5176\u5c11\u91cf\u7684\u65e0\u5b9a\u5f62\u533a\uff0c\u9502\u79bb\u5b50\u96be\u4ee5\u5728\u805a\u5408\u7269\u7684\u5206\u5b50\u957f\u94fe\u4e0a\u8fdb\u884c\u5b9a\u5411\u8fc1\u79fb\uff0c\u56e0\u6b64\u5f88\u96be\u6ee1\u8db3\u5ba4\u6e29\u6761\u4ef6\u4e0b\u7684\u5b9e\u9645\u5e94\u7528\u3002PVDF\u548cPVDF-HFP\u56e0\u5177\u6709\u76f8\u5bf9\u5bbd\u7684\u7535\u5316\u5b66\u7a97\u53e3\u3001\u826f\u597d\u7684\u70ed\u7a33\u5b9a\u6027\u548c\u8f83\u9ad8\u7684\u529b\u5b66\u5f3a\u5ea6\u7b49\u4f18\u70b9\uff0c\u4e5f\u662f\u7406\u60f3\u7684\u805a\u5408\u7269\u7535\u89e3\u8d28\u57fa\u4f53\u6750\u6599\u4e4b\u4e00\u3002Zhang\u7b49\u4eba\u62a5\u9053\u4e86\u5229\u7528\u5177\u6709\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u7684PVDF\u57fa\u56fa\u6001\u7535\u89e3\u8d28\u5b9e\u73b0\u91d1\u5c5e\u9502\u679d\u6676\u6291\u5236\u7684\u76f8\u5173\u5de5\u4f5c\u3002\u5728\u6240\u5236\u5907\u7684\u7535\u89e3\u8d28\u8584\u819c\u4e2d\uff0c\u6b8b\u4f59\u7684N\uff0cN-\u4e8c\u7532\u57fa\u7532\u9170\u80fa(DMF)\u6eb6\u5242\u5e76\u4e0d\u662f\u4ee5\u81ea\u7531\u5206\u5b50\u7684\u5f62\u5f0f\u5b58\u5728\uff0c\u800c\u662f\u4e0eLi+\u53d1\u751f\u914d\u4f4d\u5f62\u6210\u4e86[Li(DMF)x]+\u7684\u79bb\u5b50\u590d\u5408\u7269\u3002\u7531\u4e8e\u6ca1\u6709\u81ea\u7531\u6eb6\u5242\u5206\u5b50\u7684\u5b58\u5728\uff0cPVDF\u57fa\u8d28\u4f1a\u901a\u8fc7PVDF\u4e0eDMF\u4e4b\u95f4\u7684\u76f8\u4e92\u4f5c\u7528\u6765\u4f20\u5bfc[Li(DMF)x]+\u79bb\u5b50\u590d\u5408\u7269\uff0c\u8fd9\u79cd\u4f20\u5bfc\u673a\u5236\u4e0e\u5e7f\u6cdb\u7814\u7a76\u7684PEO\u590d\u5408\u7535\u89e3\u8d28\u5341\u5206\u7c7b\u4f3c\u3002PVDF\u3001\u9502\u76d0\u548c\u952e\u5408\u6001\u7684DMF\u5206\u5b50\u4e4b\u95f4\u5b58\u5728\u7740\u534f\u540c\u4f5c\u7528\u4f7f\u5f97\u7535\u89e3\u8d28\u7684\u79bb\u5b50\u7535\u5bfc\u6027\u80fd\u548c\u5168\u56fa\u6001\u7535\u6c60\u7684\u7535\u5316\u5b66\u6027\u80fd\u5f97\u5230\u5927\u5e45\u6539\u5584\u3002\u4f46\u662f\uff0c\u5bf9\u4e8eDMF\u6eb6\u5242\u6b8b\u4f59\u542b\u91cf\u7684\u7cbe\u786e\u8c03\u63a7\u4ecd\u7136\u96be\u4ee5\u628a\u63e1\u3002Xu\u7b49\u4eba\u91c7\u7528\u4e86bottom-to-up\u7684\u8bbe\u8ba1\u7b56\u7565\uff0c\u5229\u7528\u56db\u6c22\u544b\u5583\u6eb6\u5242\u6613\u4e8e\u6325\u53d1\u7684\u7279\u8d28\u6291\u5236\u4e86PVDF-HFP\u57fa\u805a\u5408\u7269\u7535\u89e3\u8d28\u5728\u5236\u5907\u8fc7\u7a0b\u4e2d\u6613\u53d1\u751f\u7684\u76f8\u5206\u79bb\u7684\u7f3a\u70b9\uff0c\u5236\u5907\u51fa\u4e86\u5355\u4e00\u76f8\u7684\u51c6\u79bb\u5b50\u6db2\u4f53\/PVDF-HFP\u81f4\u5bc6\u578b\u805a\u5408\u7269\u7535\u89e3\u8d28\uff0c\u8be5\u7535\u89e3\u8d28\u5177\u67091.55\u00d710-3 S\/cm\u7684\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\uff0c3.4 MPa\u7684\u62c9\u4f38\u5f3a\u5ea6\uff0c\u7ea61550%\u7684\u65ad\u88c2\u4f38\u957f\u7387\u3002\u6b64\u5916\uff0c\u4f5c\u8005\u8fd8\u53d1\u73b0\u6b8b\u4f59\u7684DMF\u6eb6\u5242\u5e76\u4e0d\u662f\u81ea\u7531\u5206\u5b50\uff0c\u800c\u662f\u4e0e\u9502\u76d0\u5f62\u6210\u4e86[Li(DMF)3][TFSI]\u7edc\u5408\u7269\uff0c\u6709\u6548\u63d0\u9ad8\u4e86\u7535\u89e3\u8d28\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u4e0e\u5b89\u5168\u6027\u3002<\/p>\n
\u9664\u4e86\u4ee5\u4e0a\u8fd9\u4e9b\u88ab\u5e7f\u6cdb\u7814\u7a76\u7684\u805a\u5408\u7269\u57fa\u4f53\uff0c\u8fd8\u6709\u4e00\u4e9b\u4e0d\u540c\u5206\u5b50\u91cf\u7684\u4e19\u70ef\u9178\u916f\u5355\u4f53\uff0c\u5982\u805a(\u4e59\u4e8c\u9187)\u7532\u57fa\u919a\u7532\u57fa\u4e19\u70ef\u9178\u916f(PEGMEA)\u548c\u805a\u4e59\u4e8c\u9187\u4e19\u70ef\u9178(PEGDA)\uff0c\u53ef\u4ee5\u901a\u8fc7\u5149\u56fa\u5316\u6216\u8005\u70ed\u56fa\u5316\u7684\u5f62\u5f0f\u4f7f\u7528\u539f\u4f4d\u805a\u5408\u7684\u65b9\u6cd5\u5236\u5907\u805a\u5408\u7269\u56fa\u4f53\u7535\u89e3\u8d28\uff0c\u5e76\u4e14\u79bb\u5b50\u7535\u5bfc\u7387\u53ef\u8fbe10-4 S\/cm\u7ea7\u522b\u3002\u6b64\u5916\uff0c\u8102\u80aa\u65cf\u805a\u78b3\u9178\u916f\u57fa\u7684\u805a\u5408\u7269\u56fa\u6001\u7535\u89e3\u8d28\u7531\u4e8e\u5176\u7279\u6b8a\u7684\u5206\u5b50\u7ed3\u6784\u548c\u9ad8\u4ecb\u7535\u5e38\u6570\u88ab\u8ba4\u4e3a\u662f\u4e00\u7c7b\u975e\u5e38\u5177\u6709\u524d\u9014\u7684\u805a\u5408\u7269\u7535\u89e3\u8d28\u4f53\u7cfb\u3002Chai\u7b49\u4eba\u901a\u8fc7\u6765\u81ea\u78b3\u9178\u4e19\u70ef\u916f\u6dfb\u52a0\u5242\u7684\u6b63\u9762\u754c\u9762\u6548\u5e94\u4e3a\u7075\u611f\u5236\u5907\u4e86\u4e00\u79cd\u65b0\u578b\u7684\u805a\u78b3\u9178\u4e59\u70ef\u57fa\u805a\u5408\u7269\u56fa\u4f53\u7535\u89e3\u8d28\uff0c\u8fd9\u79cd\u56fa\u4f53\u7535\u89e3\u8d28\u5177\u6709\u826f\u597d\u7684\u7535\u5316\u5b66\u7a33\u5b9a\u7a97\u53e3\u4e14\u572850 \u2103\u65f6\u79bb\u5b50\u7535\u5bfc\u7387\u8fbe\u52309.82\u00d710-5 S\/cm\uff0c\u7528\u5176\u88c5\u914d\u7684\u9ad8\u538bLiCoO2||Li\u7535\u6c60\u5177\u6709\u826f\u597d\u7684\u7535\u5316\u5b66\u6027\u80fd\u548c\u5b89\u5168\u7279\u6027\u3002\u805a\u78b3\u9178\u4e19\u70ef\u916f(PPC)\u662f\u4e00\u79cd\u7531\u4e8c\u6c27\u5316\u78b3\u548c\u73af\u6c27\u4e19\u70f7\u5171\u805a\u53cd\u5e94\u5f97\u5230\u7684\u65b0\u578b\u53ef\u964d\u89e3\u8102\u80aa\u65cf\u805a\u78b3\u9178\u916f\uff0c\u6bcf\u4e00\u4e2a\u91cd\u590d\u5355\u5143\u4e2d\u90fd\u6709\u4e00\u4e2a\u6781\u6027\u5f88\u5f3a\u7684\u78b3\u9178\u916f\u57fa\u56e2\uff0c\u5177\u6709\u4f4e\u7684\u73bb\u7483\u5316\u8f6c\u53d8\u6e29\u5ea6\u548c\u9ad8\u7684\u70ed\u5c3a\u5bf8\u7a33\u5b9a\u6027\u7b49\u4f18\u70b9\u3002Zhang\u7b49\u4eba\u53d7\u592a\u6781\u7684\u542f\u53d1\uff0c\u63d0\u51fa\u4e86\u521a\u67d4\u5e76\u6d4e\u7684\u6982\u5ff5\uff0c\u7528\u521a\u6027\u7684\u65e0\u7eba\u5e03\u591a\u5b54\u819c\u8d1f\u8f7d\u67d4\u6027\u7684\u805a\u5408\u7269\u79bb\u5b50\u4f20\u8f93\u6750\u6599PPC\u5f97\u5230\u4e86\u590d\u5408\u56fa\u4f53\u7535\u89e3\u8d28CPPC\uff0c\u5176\u5ba4\u6e29\u79bb\u5b50\u7535\u5bfc\u7387\u9ad8\u8fbe4.2\u00d710-4 S\/cm\uff0c\u8fd9\u662f\u7531\u4e8ePPC\u662f\u65e0\u5b9a\u5f62\u7ed3\u6784\u4e14\u5206\u5b50\u94fe\u6781\u6613\u53d1\u751f\u5185\u65cb\u8f6c\uff0c\u9502\u79bb\u5b50\u4e3b\u94fe\u4e0a\u7684\u7fb0\u57fa\u6c27\u7ed3\u5408\u540e\u94fe\u6bb5\u8fd0\u52a8\u8f83\u5feb\u4ece\u800c\u5bfc\u81f4\u9502\u79bb\u5b50\u7684\u5feb\u901f\u8fc1\u79fb\u3002<\/p>\n
\u56fe5\u662f\u51e0\u79cd\u4e0d\u540c\u7535\u89e3\u8d28\u7684\u5e73\u5747\u6027\u80fd\u7684\u7efc\u5408\u5206\u6790\uff0c\u5176\u4e2d\u5355\u4e00\u7535\u89e3\u8d28\u7cfb\u7edf\u603b\u662f\u663e\u793a\u51fa\u4e00\u5b9a\u7684\u5f31\u70b9\uff0c\u800c\u590d\u5408\u7535\u89e3\u8d28\u6750\u6599\u53ef\u4ee5\u663e\u8457\u6539\u5584\u6027\u80fd\u3002<\/p>\n
<\/p>\n
\u56fe5 \u4e0d\u540c\u7535\u89e3\u8d28\u7684\u5e73\u5747\u6027\u80fd\u7684\u96f7\u8fbe\u56fe\uff1a(a) \u6709\u673a\u7535\u89e3\u8d28;(b) \u56fa\u4f53\u805a\u5408\u7269\u7535\u89e3\u8d28;(c) \u56fa\u4f53\u65e0\u673a\u7535\u89e3\u8d28;(d) \u805a\u5408\u7269\/\u6db2\u4f53\u590d\u5408\u7535\u89e3\u8d28\u6750\u6599;(e) \u805a\u5408\u7269\/\u805a\u5408\u7269\u590d\u5408\u6750\u6599\u4ee5\u53ca(f) \u805a\u5408\u7269\/\u65e0\u673a\u590d\u5408\u6750\u6599<\/p>\n
3.2\u3000\u590d\u5408\u805a\u5408\u7269\u56fa\u4f53\u7535\u89e3\u8d28<\/p>\n
\u76ee\u524d\u5e38\u7528\u7684\u590d\u5408\u805a\u5408\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u5236\u5907\u7b56\u7565\u4e3b\u8981\u5305\u62ec\uff1a\u5171\u6df7\u6216\u4ea4\u8054\u3001\u52a0\u5165\u652f\u6491\u4f53\u3001\u6709\u673a\u65e0\u673a\u590d\u5408\u7b49\u3002<\/p>\n
3.2.1\u3000\u5171\u6df7\u6216\u4ea4\u8054<\/p>\n
\u5bf9\u805a\u5408\u7269\u57fa\u4f53\u8fdb\u884c\u5171\u6df7\u6216\u8005\u4ea4\u8054\uff0c\u901a\u8fc7\u964d\u4f4e\u805a\u5408\u7269\u7684\u7ed3\u6676\u5ea6\uff0c\u53ef\u4ee5\u6709\u6548\u63d0\u9ad8\u590d\u5408\u805a\u5408\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u5ba4\u6e29\u79bb\u5b50\u7535\u5bfc\u7387\u3002Lalia\u7b49\u91c7\u7528\u5171\u6df7\u5236\u5907\u4e86\u7531\u56db\u7518\u9187\u4e8c\u7532\u919a\u3001PEO\u3001\u7f51\u72b6\u7ea4\u7ef4\u7d20\u548c\u9ad8\u6c2f\u9178\u9502(LiClO4)\u7ec4\u6210\u7684\u4e09\u5143\u805a\u5408\u7269\u7535\u89e3\u8d28\u3002\u7f51\u72b6\u7ea4\u7ef4\u7d20\u548c\u56db\u7518\u9187\u4e8c\u7532\u919a\u7684\u52a0\u5165\u6709\u52a9\u4e8e\u63d0\u9ad8\u805a\u5408\u7269\u7535\u89e3\u8d28\u7684\u7535\u5bfc\u7387\u548c\u673a\u68b0\u5b8c\u6574\u6027\uff0c\u8be5\u7535\u89e3\u8d28\u7684\u5ba4\u6e29\u7535\u5bfc\u7387\u6700\u9ad8\u53ef\u8fbe10-4 S\/cm\u3002Khurana\u7b49\u62a5\u9053\u4e86\u4e00\u79cd\u901a\u8fc7\u5f00\u73af\u805a\u5408\u7528\u4fa7\u94fePEO\u4ea4\u8054\u805a\u4e59\u70ef(PE)\u4e3b\u94fe\u7684\u56fa\u4f53\u7535\u89e3\u8d28\u819c[\u56fe6(a)]\uff0c\u4ea4\u8054\u6291\u5236\u4e86PEO\u7684\u7ed3\u6676\u6027\uff0c\u4f7f\u7535\u89e3\u8d28\u5728\u5ba4\u6e29\u4e0b\u5177\u6709\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387(>1.0\u00d710-4 S\/cm)\u3002\u53e6\u5916\uff0c\u4f20\u7edf\u7684\u7406\u8bba\u8ba4\u4e3a\u7535\u89e3\u8d28\u819c\u9700\u8981\u5177\u6709\u8db3\u591f\u7684\u673a\u68b0\u5f3a\u5ea6\u4e4b\u540e\u624d\u80fd\u6709\u6548\u6291\u5236\u9502\u679d\u6676\u7684\u751f\u957f\uff0c\u4f46\u4f5c\u8005\u9996\u6b21\u8bc1\u660e\u7535\u89e3\u8d28\u819c\u6291\u5236\u9502\u679d\u6676\u751f\u957f\u7684\u80fd\u529b\u4e0e\u5176\u673a\u68b0\u5f3a\u5ea6\u4e4b\u95f4\u5e76\u4e0d\u662f\u7edd\u5bf9\u7684\u5173\u7cfb\u3002<\/p>\n
<\/p>\n
\u56fe6 (a) \u805a\u4e59\u70ef\/\u805a\u73af\u6c27\u4e59\u70f7\u56fa\u4f53\u805a\u5408\u7269\u7535\u89e3\u8d28\u7684\u5408\u6210\u4e0e\u547d\u540d;(b) \u805a\u5408\u7269\u590d\u5408\u6750\u6599SSE\u7684\u8bbe\u8ba1\u539f\u7406\u793a\u610f\u56fe(\u5de6)\uff0c\u8d85\u8584\u7eb3\u7c73\u5b54PI<\/u>\u8584\u819c\u7684\u6a2a\u65ad\u9762\u626b\u63cf\u7535\u955c\u56fe\u50cf\u548c\u6392\u5217\u6574\u9f50\u7684\u7eb3\u7c73\u5b54\u7684\u653e\u5927\u56fe\u50cf(\u53f3);(c) m-PPL\u7684\u5236\u5907\u5de5\u827a\u793a\u610f\u56fe<\/p>\n
3.2.2\u3000\u52a0\u5165\u652f\u6491\u4f53<\/p>\n
\u4e00\u822c\u6765\u8bf4\uff0c\u5355\u7eaf\u7684\u805a\u5408\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u5728\u539a\u5ea6\u548c\u5f3a\u5ea6\u65b9\u9762\u4ecd\u7136\u5dee\u5f3a\u4eba\u610f\uff0c\u800c\u52a0\u5165\u8584\u800c\u5f3a\u52b2\u7684\u81ea\u652f\u6491\u4e3b\u4f53\uff0c\u53ef\u4ee5\u5b9e\u73b0\u8f83\u5f3a\u7684\u529b\u5b66\u6027\u80fd\u4e14\u539a\u5ea6\u53ef\u63a7\u3002Wan\u7b49\u62a5\u9053\u4e86\u4e00\u79cd\u4ee5\u591a\u5b54\u805a\u9170\u4e9a\u80fa\u819c(PI)\u4e3a\u4e3b\u4f53\u3001PEO\/\u53cc(\u4e09\u6c1f\u7532\u70f7\u78fa\u9170)\u9502\u9170\u4e9a\u80fa(LiTFSI)\u4f5c\u4e3a\u586b\u5145\u7269\u7684\u8d85\u8584\u3001\u67d4\u6027\u3001\u673a\u68b0\u5f3a\u5ea6\u9ad8\u7684\u805a\u5408\u7269-\u805a\u5408\u7269SPE[\u56fe6(b)]\uff0c\u6240\u5236\u5907\u7535\u89e3\u8d28\u7684\u539a\u5ea6\u4ec5\u4e3a8.6 \u03bcm\u3002\u7531\u4e8ePI\u819c\u4e0d\u6613\u71c3\uff0c\u673a\u68b0\u5f3a\u5ea6\u9ad8\uff0c\u53ef\u4ee5\u6709\u6548\u9632\u6b62\u7535\u6c60\u5728\u5faa\u73af\u8fc7\u7a0b\u4e2d\u7531\u9502\u679d\u6676\u5f15\u53d1\u7684\u7535\u6c60\u77ed\u8def\u3002\u7ecf\u8fc7\u7269\u7406\u523b\u8680\u5f62\u6210\u7684\u5782\u76f4\u901a\u9053\u63d0\u9ad8\u4e86\u6ce8\u5165\u7684\u805a\u5408\u7269\u7535\u89e3\u8d28\u7684\u79bb\u5b50\u5bfc\u7535\u7387(30 \u2103\u4e0b2.3\u00d710-4 S\/cm)\u3002Wu\u7b49\u5229\u7528\u7b80\u5355\u7684\u6eb6\u5242\u6325\u53d1\u6cd5\u5c06PEO\/LiTFSI\u805a\u5408\u7269\u7535\u89e3\u8d28\u586b\u5145\u81f3\u805a\u4e59\u70ef\u9694\u819c\u7684\u5b54\u9053\u5185\uff0c\u5236\u5907\u4e86\u539a\u5ea6\u4ec5\u4e3a7.5 \u03bcm\u7684\u8d85\u8584\u590d\u5408\u805a\u5408\u7269\u7535\u89e3\u8d28\u3002\u8d85\u8584\u7684\u7535\u89e3\u8d28\u7f29\u77ed\u4e86\u9502\u79bb\u5b50\u5728\u7535\u89e3\u8d28\u4e2d\u7684\u6269\u6563\u65f6\u95f4\u548c\u8ddd\u79bb\uff0c\u5e76\u4e3a\u7535\u6c60\u63d0\u4f9b\u4e86\u8db3\u591f\u7684\u9502\u79bb\u5b50\u3002\u8fd9\u4e9b\u7814\u7a76\u6210\u679c\u6e05\u695a\u5730\u8868\u660e\uff0c\u901a\u8fc7\u5f15\u5165\u5f3a\u57fa\u4f53\u819c\uff0c\u805a\u5408\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u7535\u5316\u5b66\u548c\u529b\u5b66\u6027\u80fd\u5f97\u5230\u4e86\u663e\u8457\u63d0\u9ad8\u3002\u4e3a\u4e86\u8fdb\u4e00\u6b65\u6539\u5584\u7535\u89e3\u8d28\u548c\u7535\u6781\u4e4b\u95f4\u7684\u754c\u9762\u517c\u5bb9\u6027\uff0cWang\u7b49\u62a5\u9053\u4e86\u4e00\u79cd\u4ee5\u6539\u6027PE\u4e3a\u4e3b\u4f53\uff0c\u805a\u4e59\u4e8c\u9187\u7532\u57fa\u919a\u4e19\u70ef\u9178\u916f(PEGMEA)\u548c\u9502\u76d0\u4e3a\u586b\u6599\u768410 \u03bcm\u539a\u8d85\u8584\u805a\u5408\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u3002\u591a\u5b54\u7684\u805a\u7532\u57fa\u4e19\u70ef\u9178\u7532\u916f-\u805a\u82ef\u4e59\u70ef(PMMA-PS)\u754c\u9762\u5c42\u7d27\u5bc6\u8d34\u5408\u5728PE\u7684\u4e24\u4fa7\uff0c\u6709\u6548\u5730\u6539\u5584\u4e86\u7535\u89e3\u8d28\u548c\u7535\u6781\u4e4b\u95f4\u7684\u754c\u9762\u76f8\u5bb9\u6027\uff0c\u89c1\u56fe6(c)\u3002<\/p>\n
3.2.3\u3000\u6709\u673a-\u65e0\u673a\u590d\u5408\u805a\u5408\u7269\u56fa\u4f53\u7535\u89e3\u8d28<\/p>\n
\u5bf9\u4e8e\u805a\u5408\u7269\/\u65e0\u673a\u7269\u7684\u590d\u5408\u7535\u89e3\u8d28\u6750\u6599\u6765\u8bf4\uff0c\u65e9\u671f\u7684\u7814\u7a76\u57fa\u672c\u90fd\u56f4\u7ed5\u5728\u60f0\u6027\u586b\u6599\u4e0a\u3002Croce\u7b49\u5c06\u9676\u74f7\u7eb3\u7c73\u9897\u7c92(5.8\uff5e13 nm)\u9996\u6b21\u5f15\u5165\u5230PEO\u57fa\u805a\u5408\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u3002\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u63d0\u9ad8\u4e863\u4e2a\u6570\u91cf\u7ea7\uff0c\u572830 \u2103\u8fbe\u523010-5 S\/cm\u7ea7\u522b\uff0c\u8fd9\u662f\u5f97\u76ca\u4e8e\u9676\u74f7\u7eb3\u7c73\u9897\u7c92\u5927\u7684\u8868\u9762\u79ef\u548c\u8def\u6613\u65af\u9178\u7684\u7efc\u5408\u6548\u5e94\u7684\u7279\u70b9\uff0c\u53ef\u4ee5\u9632\u6b62PEO\u94fe\u5728\u51b7\u5374\u8fc7\u7a0b\u4e2d(\u4ece\u9ad8\u4e8e60 \u2103\u5230\u73af\u5883\u6e29\u5ea6)\u518d\u7ed3\u6676\u3002\u5728\u805a\u5408\u7269\u7535\u89e3\u8d28\u4e2d\u63ba\u6742\u60f0\u6027\u586b\u6599\u53ef\u4ee5\u6709\u6548\u964d\u4f4e\u805a\u5408\u7269\u7535\u89e3\u8d28\u7684\u73bb\u7483\u5316\u8f6c\u53d8\u6e29\u5ea6\uff0c\u6b64\u5916\u65e0\u673a\u586b\u6599\u7684\u52a0\u5165\u53ef\u4ee5\u6709\u6548\u6539\u5584\u7535\u89e3\u8d28\u7684\u529b\u5b66\u6027\u80fd\u3002\u8fd1\u5341\u5e74\u6765\uff0c\u7814\u7a76\u8005\u4eec\u7684\u76ee\u5149\u66f4\u591a\u5730\u8f6c\u5411\u4e86\u6d3b\u6027\u586b\u6599\uff0c\u4f8b\u5982Li1+xAlxTi2-x(PO4)3(LATP)\uff0cLi6.75La3Zr1.75Ta0.25O12(LLZTO)\u7b49\u3002\u6d3b\u6027\u586b\u6599\u5373\u53c2\u4e0e\u5bfc\u7535\u8fc7\u7a0b\u7684\u586b\u6599\uff0c\u7531\u4e8e\u5176\u672c\u8eab\u80fd\u591f\u63d0\u4f9b\u5bfc\u7535\u7684\u9502\u79bb\u5b50\uff0c\u9502\u79bb\u5b50\u4e0d\u4ec5\u53ef\u4ee5\u5728\u805a\u5408\u7269\u76f8\u4e2d\u8f6c\u79fb\uff0c\u8fd8\u53ef\u4ee5\u5728\u6d3b\u6027\u586b\u6599\u76f8\u4e2d\u8f6c\u79fb\uff0c\u8fd9\u6837\u805a\u5408\u7269\u7535\u89e3\u8d28\u7684\u7535\u5bfc\u7387\u5c06\u4f1a\u6709\u6548\u63d0\u9ad8\u3002Huang\u7b49\u901a\u8fc7\u70e7\u7ed3\u5236\u5907\u51fa\u5177\u6709\u8054\u9501\u591a\u5b54\u7ed3\u6784\u7684Li0.33La0.557TiO3(LLTO)\u9aa8\u67b6\u6750\u6599\uff0c\u968f\u540e\u5c06\u805a\u73af\u6c27\u4e59\u70f7(PEO)\u5f15\u5165\u5b54\u4e2d\uff0c\u751f\u6210\u5177\u6709\u5782\u76f4\u53cc\u8fde\u7eed\u76f8\u7684PEO-LLTO\u6846\u67b6\u56fa\u4f53\u7535\u89e3\u8d28\uff0c\u79bb\u5b50\u7535\u5bfc\u7387\u9ad8\u8fbe2.04\u00d710-4 S\/cm\u3002\u8be5\u7814\u7a76\u8868\u660eLLTO\u6846\u67b6\u80fd\u591f\u901a\u8fc7\u5185\u5728\u7a7a\u4f4d\u5feb\u901f\u4f20\u8f93Li+\uff0c\u540c\u65f6\u4f4e\u6676\u5316\u7684PEO\u8868\u73b0\u51fa\u5feb\u901fLi+\u8f6c\u79fb\u80fd\u529b\uff0c\u534f\u540c\u5b9e\u73b0\u9ad8\u6548Li+\u5bfc\u7535\u3002Hu\u7b49\u53d1\u660e\u4e86\u4e00\u79cd\u65b0\u9896\u7684\u540c\u6b65\u9759\u7535\u7eba\u4e1d\/\u9759\u7535\u55b7\u96fe\u65b9\u6cd5\u6765\u5236\u5907\u5bcc\u6709\u8fde\u7eed\u754c\u9762\u7684\u8584\u819c\u8d85\u79bb\u5b50\u5bfc\u4f53\u3002\u7531LLZTO\u548cPAN\u6240\u7ec4\u6210\u7684\u8d85\u5feb\u9502\u79bb\u5b50\u5bfc\u4f53\u572825 \u2103\u4e0b\u53ef\u5b9e\u73b01.18\u00d710-3 S\/cm\u7684\u79bb\u5b50\u7535\u5bfc\u7387\uff0c\u8d85\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u7684\u5173\u952e\u5728\u4e8e\u6784\u5efa\u4e86\u5927\u91cf\u7684\u8fde\u7eed\u754c\u9762\uff0c\u4f7f\u5feb\u901f\u754c\u9762\u4f20\u5bfc\u6210\u4e3a\u4e3b\u5bfc\u673a\u5236\u3002\u8fd9\u79cd\u65b0\u578b\u7684\u4f53\u754c\u9762\u8d85\u79bb\u5b50\u5bfc\u4f53\u53ef\u4f7f\u56fa\u6001\u7535\u6c60\u5728\u5ba4\u6e29\u4e0b\u5b9e\u73b0\u4f4e\u7684\u6781\u5316\u4ee5\u53ca\u957f\u7684\u5faa\u73af\u5bff\u547d\u3002Ju\u7b49\u901a\u8fc7\u539f\u4f4d\u805a\u5408\u5236\u5907\u4e86\u805a\u78b3\u9178\u916f(PVCA)\u4e0eLi10SnP2S12(LSnPS)\u7684\u590d\u5408\u56fa\u4f53\u7535\u89e3\u8d28\uff0c\u805a\u5408\u540e\u5f97\u5230\u4e86\u5177\u6709\u826f\u597d\u5ba4\u6e29\u7535\u5bfc\u7387\u548c\u5bbd\u7535\u5316\u5b66\u7a97\u53e3\u7684PVCA-LSnPS\u590d\u5408\u7535\u89e3\u8d28\u3002\u66f4\u91cd\u8981\u7684\u662f\u590d\u5408\u7535\u89e3\u8d28\u548c\u9502\u91d1\u5c5e\u8d1f\u6781\u4ee5\u53ca\u56fa\u6001\u6b63\u6781\u4e4b\u95f4\u90fd\u5c55\u73b0\u51fa\u826f\u597d\u7684\u517c\u5bb9\u6027\uff0c\u6781\u5927\u5730\u964d\u4f4e\u4e86\u7535\u6c60\u7684\u754c\u9762\u963b\u6297\uff0c\u4ece\u800c\u83b7\u5f97\u4e86\u4f18\u5f02\u7684\u7535\u5316\u5b66\u6027\u80fd\u3002<\/p>\n
4 \u787c\u6c22\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28<\/p>\n
4.1\u3000\u787c\u6c22\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u7814\u7a76\u8fdb\u5c55<\/p>\n
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<\/p>\n
\u56fe7 (a) LiBH4\u548cLiBH4-LiX(X = Cl\uff0cBr\uff0cI)\u7535\u5bfc\u7387\u548c\u6e29\u5ea6\u7684\u5173\u7cfb;(b) Li2(BH4)(NH2)\u548cLi4(BH4)(NH2)3 \u79bb\u5b50\u7535\u5bfc\u7387\u548c\u6e29\u5ea6\u7684\u5173\u7cfb<\/p>\n
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S\/cm\u3002\u6b64\u5916\uff0c\u76f4\u6d41\u7535\u5bfc\u7387\u6d4b\u91cf<\/u>\u8868\u660e\u4e24\u8005\u9633\u79bb\u5b50\u8fc1\u79fb\u6570\u63a5\u8fd1\u4e8e1\u30022016\u5e74\uff0cTang\u7b49\u8fdb\u4e00\u6b65\u53d1\u73b0LiCB9H10\u548cNaCB9H10\u53ef\u4ee5\u5728\u5ba4\u6e29\u6216\u8005\u4e34\u754c\u5ba4\u6e29\u7684\u6e29\u5ea6\u4e0b\u4fdd\u6301\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\u7684\u516d\u65b9\u76f8\uff0c\u4ece\u800c\u5c55\u73b0\u51fa\u5ab2\u7f8e\u6709\u673a\u6db2\u4f53\u7535\u89e3\u8d28\u7684\u79bb\u5b50\u7535\u5bfc\u7387(0.03 S\/cm)\u3002\u4e3a\u4e86\u8fdb\u4e00\u6b65\u63d0\u9ad8\u79bb\u5b50\u7535\u5bfc\u7387\uff0cTang\u7b49\u901a\u8fc7\u590d\u5408CB9H<\/p>\n \u6216CB11H<\/p>\n 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\u5364\u5316\u7269\u7535\u89e3\u8d28\u7ecf\u5386\u4e86\u51e0\u5341\u5e74\u53d1\u5c55\uff0c\u7531\u4e8e\u5176\u4f4e\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u4e00\u76f4\u672a\u53d7\u91cd\u89c6\uff0c\u4f46\u662f\u6700\u8fd1\u5341\u5e74\u5c24\u5176\u662f\u6700\u8fd1\u56db\u5e74\u4ee5\u6765\uff0c\u591a\u4e2a\u6750\u6599\u7684\u5ba4\u6e29\u79bb\u5b50\u7535\u5bfc\u7387\u5747\u5b9e\u73b0\u4e86\u5927\u4e8e1\u00d710-3 S\/cm \u7684\u7a81\u7834\uff0c\u518d\u7ed3\u5408\u5176\u826f\u597d\u7684\u5316\u5b66\/\u7535\u5316\u5b66\u7a33\u5b9a\u6027\uff0c\u4ee5\u53ca\u5176\u6750\u6599\u672c\u8eab\u826f\u597d\u7684\u53ef\u5851\u6027\uff0c\u56e0\u6b64\u5364\u5316\u7269\u7535\u89e3\u8d28\u4e5f\u662f\u5c06\u6765\u56fa\u6001\u9502\u7535\u6c60\u5b9e\u73b0\u5927\u89c4\u6a21\u5e94\u7528\u7684\u4e00\u79cd\u6f5c\u5728\u7684\u5019\u9009\u6750\u6599\u3002\u7efc\u4e0a\uff0c\u7ecf\u8fc7\u6700\u8fd1\u51e0\u5341\u5e74\u5c24\u5176\u662f\u6700\u8fd1\u5341\u5e74\u7684\u53d1\u5c55\uff0c\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u53d1\u5c55\u53d6\u5f97\u4e86\u5de8\u5927\u7684\u8fdb\u5c55\uff0c\u5404\u7c7b\u65b0\u9896\u7684\u5236\u5907\u65b9\u6cd5\u4e5f\u4e0d\u65ad\u6d8c\u73b0\uff0c\u88683\u5217\u4e3e\u4e86\u6700\u8fd1\u5341\u5e74\u5177\u6709\u4ee3\u8868\u6027\u7684\u7535\u89e3\u8d28\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u4ee5\u53ca\u5236\u5907\u65b9\u9762\u7684\u8fdb\u5c55\u3002<\/p>\n \u88683 \u4e0d\u540c\u7c7b\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u79bb\u5b50\u7535\u5bfc\u7387\u4ee5\u53ca\u5236\u5907\u65b9\u6cd5<\/p>\n <\/p>\n 6 \u754c\u9762\u95ee\u9898\u673a\u7406\u5206\u6790\u4e0e\u6539\u6027\u7b56\u7565<\/p>\n 6.1\u3000\u754c\u9762\u95ee\u9898\u4ea7\u751f\u673a\u7406<\/p>\n 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7535\u5b50\u7535\u5bfc\u7387\u8f83\u4f4e\u65f6\uff0c\u4f1a\u5f62\u6210\u4e9a\u7a33\u6001\u754c\u9762\uff0c\u8fd9\u548c\u4f20\u7edf\u7535\u6c60\u4e2dSEI\u819c\u7684\u5f62\u6210\u8fc7\u7a0b\u7c7b\u4f3c\u3002\u9664\u4e86\u56fa\u4f53\u7535\u89e3\u8d28\u548c\u9502\u8d1f\u6781\u7684\u754c\u9762\u53cd\u5e94\u4e4b\u5916\uff0c\u8fd1\u5e74\u6765\uff0c\u9502\u679d\u6676\u5728\u56fa\u4f53\u7535\u89e3\u8d28\u4e2d\u7684\u751f\u957f\u8d8a\u6765\u8d8a\u5f15\u8d77\u4e86\u4eba\u4eec\u7684\u91cd\u89c6\u3002\u5f53\u7535\u6d41\u5bc6\u5ea6\u548c\u9762\u5bb9\u91cf\u8fc7\u5927\u65f6\uff0c\u9502\u91d1\u5c5e\u4f1a\u5728\u56fa\u4f53\u7535\u89e3\u8d28\u7684\u5185\u90e8\u548c\u6676\u754c\u5904\u4f18\u5148\u6210\u6838\u751f\u957f\uff0c\u5e76\u8fdb\u4e00\u6b65\u6e17\u900f\u5230\u5176\u4e2d\uff0c\u5bfc\u81f4\u7535\u6c60\u5931\u6548\u3002<\/p>\n 6.2\u3000\u754c\u9762\u95ee\u9898\u6539\u6027\u7b56\u7565<\/p>\n 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\u786b\u5316\u7269\u7535\u89e3\u8d28\u7531\u4e8e\u673a\u68b0\u5f3a\u5ea6\u4f4e\u3001\u53ef\u5851\u6027\u9ad8\uff0c\u56e0\u6b64\u590d\u5408\u7535\u6781\u548c\u56fa\u4f53\u7535\u89e3\u8d28\u5c42\u90fd\u53ef\u4ee5\u901a\u8fc7\u51b7\u538b\u5236\u5907\u3002\u4f46\u662f\u7531\u4e8e\u786b\u5316\u7269\u548c\u6c27\u5316\u7269\u6b63\u6781\u95f4\u591a\u5b58\u5728\u754c\u9762\u53cd\u5e94\uff0c\u56e0\u6b64\u901a\u8fc7\u5bf9\u6b63\u6781\u6216\u8005\u786b\u5316\u7269\u7535\u89e3\u8d28\u8fdb\u884c\u754c\u9762\u6539\u6027\u53ef\u4ee5\u6709\u6548\u964d\u4f4e\u754c\u9762\u963b\u6297\u3002Li\u7b49\u91c7\u7528\u539f\u5b50\u5c42\u6c89\u79ef\u6280\u672f\u5c06LiNbOx(LNO)\u5305\u8986LiNi0.8Mn0.1Co0.1O2(NCM811)\u6b63\u6781[(\u56fe10(a)]\uff0c\u5176\u4e0eLi10GeP2S12\u7684\u754c\u9762\u7a33\u5b9a\u6027\u5f97\u5230\u4e86\u6781\u5927\u7684\u63d0\u9ad8\u3002\u5f53LiNbOx\u7f13\u51b2\u5c42\u539a\u5ea6\u4e3a5 nm\u65f6\uff0c\u5176\u7535\u5316\u5b66\u6027\u80fd\u6700\u597d\uff0c\u4e0e\u672a\u5305\u8986\u7684LiNi0.8Mn0.1Co0.1O2\u7684\u7535\u6781\u76f8\u6bd4\uff0c\u5305\u8986\u540e\uff0c\u7535\u6781\u4e0e\u7535\u89e3\u8d28\u754c\u9762\u7a33\u5b9a\uff0c\u754c\u9762\u963b\u529b\u5c0f\uff0c\u5faa\u73af\u7a33\u5b9a\u6027\u660e\u663e\u63d0\u9ad8\u3002Tatsumisago\u7684\u56e2\u961f\u5728\u8fd9\u65b9\u9762\u4e5f\u505a\u4e86\u5927\u91cf\u5de5\u4f5c\u6765\u7f13\u548c\u6b63\u6781\u548c\u7535\u89e3\u8d28\u4e4b\u95f4\u7684\u754c\u9762\u963b\u6297\u3002\u4ee5Li3PO4\u8584\u819c\u4e3a\u4f8b\uff0c\u901a\u8fc7\u5ba4\u6e29\u6fc0\u5149\u8109\u51b2\u6c89\u79ef\u7684\u65b9\u6cd5\u5728LiNi0.5Mn1.5O4\u6b63\u6781\u4e0a\u6c89\u79ef\u4e86\u4e00\u5c42Li3PO4\u8584\u819c[\u56fe10(b)]\uff0c\u7ec4\u88c5\u6210\u56fa\u6001\u7535\u6c60\u540e\uff0c\u672a\u5305\u8986\u7684LiNi0.5Mn1.5O4\u65e0\u6cd5\u5b9e\u73b0\u53ef\u9006\u5faa\u73af\uff0c\u800c\u5305\u8986\u540e\u7684\u5faa\u73af\u826f\u597d\uff0c\u663e\u7136\uff0cLi3PO4\u7f13\u51b2\u5c42\u660e\u663e\u964d\u4f4e\u4e86\u6b63\u6781\u548c\u7535\u89e3\u8d28\u4e4b\u95f4\u7684\u754c\u9762\u7535\u963b\u3002\u6700\u8fd1\uff0c\u4e00\u4e9b\u65b0\u578b\u7684\u6c27\u5316\u7269\u4e5f\u88ab\u7528\u4e8e\u5305\u8986\u9ad8\u538b\u6b63\u6781\u4ee5\u63d0\u9ad8\u5176\u548c\u786b\u5316\u7269\u7535\u89e3\u8d28\u95f4\u7684\u754c\u9762\u7a33\u5b9a\u6027\uff0cCao\u7b49\u91c7\u7528\u7b80\u5355\u7684\u6e7f\u5316\u5b66\u65b9\u6cd5\uff0c\u5728LiNi1\/3Mn1\/3Co1\/3O2\u548cLi6PS5Cl\u4e4b\u95f4\u7684\u754c\u9762\u4e0a\u5305\u8986\u4e86\u4e00\u5c4215\uff5e20 nm\u7684\u975e\u6676\u6001Li0.35La0.5Sr0.05TiO3\u3002\u5728\u975e\u6676Li0.35La0.5Sr0.05TiO3\u7684\u4fdd\u62a4\u4e0b\uff0cLi6PS5Cl\u7684\u5206\u89e3\u5f97\u5230\u4e86\u6709\u6548\u6291\u5236\uff0c\u56e0\u6b64\u5927\u5927\u964d\u4f4e\u4e86\u754c\u9762\u963b\u6297\u3002Wang\u7b49\u5229\u7528LiCoO2\u548cTiO2\uff0cLiCO3\u4e4b\u95f4\u7684\u6c27\u5316\u8fd8\u539f\u53cd\u5e94\u5728LiCoO2\u8868\u9762\u539f\u4f4d\u5f62\u6210\u4e86\u4e00\u5c42\u8d85\u8584\u7684Li2CoTi3O8\u5c42\u3002\u7531\u4e8eLi2CoTi3O8\u7684\u5f15\u5165\u800c\u4ea7\u751f\u7684Li2CoTi3O8\/LGPS\u65b0\u754c\u9762\u4e0e\u539f\u59cbLiCoO2\/LGPS\u754c\u9762\u76f8\u6bd4\u5177\u6709\u66f4\u5f3a\u7684\u5316\u5b66\u4eb2\u548c\u529b\uff0c\u56e0\u6b64\u6781\u5927\u5730\u964d\u4f4e\u4e86Li2CoTi3O8\/LGPS\u7684\u754c\u9762\u963b\u6297\uff0c\u6709\u6548\u63d0\u5347\u4e86\u7535\u6c60\u7684\u5faa\u73af\u7a33\u5b9a\u6027\u3002<\/p>\n <\/p>\n \u56fe10 (a) LNO\u5305\u8986NCM811\u9897\u7c92\u622a\u9762SEM\u56fe\u8c31;(b) Li3PO4\u5305\u8986LiNi0.5Mn0.5O4\u9897\u7c92SEM\u56fe\u8c31<\/p>\n \u5bf9\u4e8e\u6c27\u5316\u7269\u7535\u89e3\u8d28\uff0c\u4e3a\u4e86\u907f\u514d\u6df7\u5408\u6b63\u6781\u70e7\u7ed3\u8fc7\u7a0b\u4e2d\u7535\u89e3\u8d28\u548c\u6b63\u6781\u95f4\u7684\u754c\u9762\u53cd\u5e94\uff0c\u6784\u5efa\u7a33\u5b9a\u6df7\u5408\u5bfc\u7535\u754c\u9762\uff0c\u964d\u4f4e\u754c\u9762\u963b\u6297\uff0c\u5e94\u8be5\u53d1\u5c55\u81ea\u9650\u6027\u7684\u754c\u9762\u5f62\u6210\u65b9\u6cd5\uff0c\u63a7\u5236\u754c\u9762\u5c42\u7684\u539a\u5ea6\u4ee5\u4fdd\u8bc1\u6c27\u5316\u7269\u56fa\u4f53\u7535\u89e3\u8d28\u548c\u6d3b\u6027\u7269\u8d28\u95f4\u7535\u8377\u7684\u8f93\u8fd0\u3002Han\u7b49\u53d1\u73b0\u6dfb\u52a0\u5c11\u91cf\u7684B2O3\u4f5c\u4e3a\u52a9\u6eb6\u5242\u53ef\u4ee5\u6709\u6548\u5730\u964d\u4f4eLATP\u7684\u70e7\u7ed3\u6e29\u5ea6(B2O3\u63ba\u6742\u91cf\u4e3a1%\uff0c\u751f\u6210\u4ea7\u7269\u7f29\u5199LABTP)\uff0c\u5e76\u6709\u52a9\u4e8e\u5728LATP\/LCO\u4e4b\u95f4\u5f62\u6210\u8584\u7684\u3001\u8fde\u7eed\u7684\u6df7\u5408\u5bfc\u7535\u754c\u9762(LABTP\/LCO-LABTP)(\u56fe11)\u3002\u7ed3\u679c\u8868\u660e\u8fde\u7eed\u5bfc\u7535\u754c\u9762\u76f8\u7684\u5f62\u6210\u6781\u5927\u5730\u6539\u5584\u4e86\u8f7d\u6d41\u5b50\u7684\u8f93\u8fd0\u6027\u8d28\uff0c\u590d\u5408\u6b63\u6781\u8d1f\u8f7d\u9762\u5bb9\u91cf\u9ad8\u8fbe6 mAh\/cm\u3002\u6b64\u5916\uff0c\u8fd9\u79cd\u65b9\u6cd5\u540c\u6837\u9002\u7528\u4e8e\u9ad8\u954d\u6b63\u6781\uff0c\u8d1f\u8f7d\u9762\u5bb9\u91cf\u9ad8\u8fbe10 mAh\/cm2\uff0c\u5e76\u6709\u671b\u5b9e\u73b0\u8d28\u91cf\u6bd4\u80fd\u91cf\u5927\u4e8e400 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<\/p>\n \u56fe11 (a) \u539f\u4f4d\u5f62\u6210\u754c\u9762\u7684\u5171\u70e7\u7ed3\u590d\u5408\u6b63\u6781\u793a\u610f\u56fe;(b) LABTP\/LCO-LABTP\u754c\u9762SEM\u56fe\u8c31\u548c\u754c\u9762\u5904\u5143\u7d20\u7ebf\u626b\u63cf\u56fe\u8c31<\/p>\n 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<\/p>\n \u56fe13 (a) \u6d41\u5ef6\u6cd5\u5236\u5907LLTO\u819c\u793a\u610f\u56fe;(b) \u590d\u5408\u786b\u5316\u7269\u7535\u89e3\u8d28\/NCM\u6b63\u6781\u819c\u793a\u610f\u56fe<\/p>\n 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7.4\u3000\u9ad8\u9762\u5bb9\u91cf\u6b63\u6781<\/p>\n \u4e3a\u4e86\u63d0\u9ad8\u6d3b\u6027\u7269\u8d28\u7684\u8d1f\u8f7d\u91cf\uff0c\u7814\u7a76\u8005\u4eec\u4e5f\u5c1d\u8bd5\u4e86\u4e0d\u540c\u7b56\u7565\u548c\u65b9\u6cd5\u3002\u4e09\u7ef4\u591a\u5b54\u9676\u74f7\u9aa8\u67b6\u56e0\u5177\u6709\u8fde\u7eed\u7684\u9502\u79bb\u5b50\u5feb\u901f\u4f20\u5bfc\u7f51\u7edc\uff0c\u4e14\u5176\u81ea\u652f\u6491\u7ed3\u6784\u80fd\u591f\u9632\u6b62\u65e0\u673a\u9897\u7c92\u7684\u56e2\u805a\uff0c\u8fd1\u5e74\u6765\u4f5c\u4e3a\u65e0\u673a\u586b\u6599\u88ab\u5e7f\u6cdb\u5730\u5e94\u7528\u4e8e\u590d\u5408\u7535\u89e3\u8d28\u4e2d\u3002Fu\u7b49\u5236\u5907\u4e86\u4e00\u79cd\u4e09\u7ef4\u53cc\u5c42\u77f3\u69b4\u77f3(Li7La3Zr2O12)\u56fa\u4f53\u7535\u89e3\u8d28\u6846\u67b6(\u56fe14)\u3002\u8fd9\u79cd\u53cc\u5c42\u56fa\u4f53\u7535\u89e3\u8d28\u7531\u9ad8\u6e29\u70ed\u538b\u70e7\u7ed3\u7684\u81f4\u5bc6\u5c42\u548c\u4e09\u7ef4\u7684\u591a\u5b54\u5c42\u7ec4\u6210\uff0c\u81f4\u5bc6\u5c42\u539a\u5ea6\u4ec5\u4e3a30 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(NCM811)\u6b63\u6781\u7684\u5bbf\u4e3b\uff0c\u81f4\u5bc6\u7684LAGP\u8584\u5c42\u7528\u4e8e\u79bb\u5b50\u4f20\u5bfc\u53ef\u6291\u5236\u679d\u6676\u751f\u957f\uff0c\u6b64\u5916\u8fd8\u5728LAGP\u548c\u9502\u91d1\u5c5e\u754c\u9762\u5904\u5f15\u5165\u4e86\u4e00\u5c42\u805a\u5408\u7269\u7535\u89e3\u8d28\u4ee5\u6539\u5584\u548c\u9502\u8d1f\u6781\u7684\u63a5\u89e6\u95ee\u9898\u3002\u5728\u8fd9\u79cd\u7ed3\u6784\u4e0b\uff0c\u591a\u5b54\u7684LAGP\u5c42\u7684\u6b63\u6781\u8d1f\u8f7d\u91cf\u53ef\u8fbe13.1 mg\/cm2\uff0c0.1 C\u7535\u6d41\u4e0b\u53ef\u63d0\u4f9b2.01 mAh\/cm2\u7684\u53ef\u9006\u9762\u5bb9\u91cf\uff0c\u5faa\u73af50\u6b21\u7684\u4fdd\u6301\u7387\u7ea6\u4e3a70.0%\uff0c\u800c\u4f20\u7edf\u7684\u4e8c\u7ef4\u7535\u6781\u53ea\u80fd\u63d0\u4f9b0.11 mAh\/cm2\u7684\u4f4e\u9762\u79ef\u5bb9\u91cf\uff0c\u4e14\u5bb9\u91cf\u5feb\u901f\u8870\u51cf\u3002<\/p>\n <\/p>\n \u56fe14 (a) \u65b0\u578b\u53cc\u5c42\u56fa\u4f53\u7535\u89e3\u8d28\u6846\u67b6\u4e0e\u4f20\u7edf\u7684\u805a\u5408\u7269\u9694\u819c\u4ee5\u53ca\u521a\u6027\u56fa\u4f53\u7535\u89e3\u8d28\u5bf9\u6bd4\u793a\u610f\u56fe;(b) \u53cc\u5c42\u56fa\u4f53\u7535\u89e3\u8d28\u70e7\u7ed3\u540e\u7167\u7247;(c) \u53cc\u5c42\u56fa\u4f53\u7535\u89e3\u8d28\u70e7\u7ed3\u540e\u754c\u9762SEM\u56fe\u8c31<\/p>\n 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